How does Low Basicity Polyaluminum Chloride react with different types of pollutants in water?

Oct 15, 2025

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James Lee
James Lee
I am a Technical Sales Engineer at Zibo Dingqi Chemicals, providing expertise in the application of water treatment chemicals such as aluminum sulfate and ferrous sulfate for municipal and industrial use.

As a supplier of Low Basicity Polyaluminum Chloride, I've witnessed firsthand the remarkable versatility and effectiveness of this chemical in water treatment. In this blog post, I'll delve into how Low Basicity Polyaluminum Chloride reacts with different types of pollutants in water, shedding light on its unique mechanisms and applications.

Understanding Low Basicity Polyaluminum Chloride

Low Basicity Polyaluminum Chloride is a coagulant widely used in water treatment processes. Its basicity, which refers to the degree of hydrolysis of the aluminum salt, is relatively low compared to other types of polyaluminum chloride, such as Medium Basicity Polyaluminum Chloride. This characteristic gives it distinct properties and reactivity patterns when interacting with pollutants in water.

Reaction with Suspended Solids

One of the primary functions of Low Basicity Polyaluminum Chloride is to remove suspended solids from water. When added to water, the positively charged aluminum ions in the coagulant neutralize the negative charges on the surface of suspended particles. This neutralization reduces the electrostatic repulsion between the particles, allowing them to come closer together and form larger aggregates, known as flocs.

The formation of flocs is crucial for the subsequent sedimentation or filtration processes. Larger flocs are easier to separate from the water, either by settling under the influence of gravity or by being trapped in a filter medium. The low basicity of the coagulant promotes the formation of denser and more compact flocs, which settle more rapidly and are more effectively removed from the water.

Reaction with Organic Pollutants

Organic pollutants, such as humic acids, proteins, and fats, are commonly found in natural water sources and wastewater. Low Basicity Polyaluminum Chloride can react with these organic pollutants through several mechanisms.

Firstly, the aluminum ions in the coagulant can form complexes with the organic molecules. These complexes are often less soluble in water and tend to precipitate out, removing the organic pollutants from the solution. Secondly, the coagulant can adsorb the organic molecules onto the surface of the flocs formed during the coagulation process. This adsorption reduces the concentration of organic pollutants in the water and improves its clarity.

In addition, Low Basicity Polyaluminum Chloride can also enhance the biodegradability of organic pollutants. By breaking down large organic molecules into smaller fragments, the coagulant makes it easier for microorganisms to degrade the pollutants during subsequent biological treatment processes.

Reaction with Heavy Metals

Heavy metals, such as lead, mercury, cadmium, and chromium, are toxic pollutants that can pose serious health risks to humans and the environment. Low Basicity Polyaluminum Chloride can react with heavy metals in water through precipitation and adsorption mechanisms.

The aluminum ions in the coagulant can react with the heavy metal ions to form insoluble metal hydroxides or oxides. These precipitates can then be removed from the water through sedimentation or filtration. In addition, the flocs formed during the coagulation process can adsorb the heavy metal ions onto their surface, further reducing the concentration of heavy metals in the water.

Reaction with Phosphates

Phosphates are nutrients that can cause eutrophication in water bodies, leading to excessive growth of algae and other aquatic plants. Low Basicity Polyaluminum Chloride can react with phosphates in water through precipitation and adsorption mechanisms.

The aluminum ions in the coagulant can react with the phosphate ions to form insoluble aluminum phosphate. This precipitate can then be removed from the water through sedimentation or filtration. In addition, the flocs formed during the coagulation process can adsorb the phosphate ions onto their surface, further reducing the concentration of phosphates in the water.

Applications of Low Basicity Polyaluminum Chloride

Low Basicity Polyaluminum Chloride has a wide range of applications in water treatment, including:

  • Drinking water treatment: It is used to remove suspended solids, organic pollutants, and heavy metals from raw water to produce safe and clean drinking water.
  • Wastewater treatment: It is used to treat industrial wastewater, municipal sewage, and agricultural runoff to remove pollutants and reduce the environmental impact of wastewater discharge.
  • Swimming pool water treatment: It is used to clarify the water and remove impurities, such as suspended solids, bacteria, and algae, to maintain the water quality of swimming pools.
  • Paper and pulp industry: It is used as a retention and drainage aid in the papermaking process to improve the efficiency of paper production and reduce the consumption of raw materials.

Advantages of Low Basicity Polyaluminum Chloride

Compared to other types of coagulants, Low Basicity Polyaluminum Chloride offers several advantages:

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  • High efficiency: It can effectively remove a wide range of pollutants from water, including suspended solids, organic pollutants, heavy metals, and phosphates, with a relatively low dosage.
  • Good flocculation performance: It promotes the formation of dense and compact flocs, which settle rapidly and are easily removed from the water.
  • Low corrosion: It has a relatively low corrosiveness to equipment and pipelines, reducing the maintenance cost of water treatment facilities.
  • Wide pH range: It can work effectively in a wide pH range, from 5 to 9, making it suitable for a variety of water treatment applications.

Conclusion

Low Basicity Polyaluminum Chloride is a versatile and effective coagulant that can react with different types of pollutants in water through various mechanisms. Its ability to remove suspended solids, organic pollutants, heavy metals, and phosphates makes it an essential component in many water treatment processes.

As a supplier of Low Basicity Polyaluminum Chloride, I'm committed to providing high-quality products and excellent customer service. If you're interested in learning more about our products or have any questions about water treatment, please feel free to contact us for procurement and further discussions.

References

  • Letterman, R. D. (2014). Water Quality and Treatment: A Handbook of Community Water Supplies. McGraw-Hill Education.
  • Metcalf & Eddy (2014). Wastewater Engineering: Treatment and Reuse. McGraw-Hill Education.
  • USEPA (2018). Drinking Water Treatment Technologies: A Summary of Available Processes. United States Environmental Protection Agency.
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